Ammonia → HCID 15175539, compound

HRID 1464109Notes

Reaction equation

HRID 1464109 reaction equation
[F:1][C:2]1[CH:3]=[C:4]([C:8]2[C:9]([N:14]=[C:15]=[S:16])=[CH:10][CH:11]=[CH:12][CH:13]=2)[CH:5]=[CH:6][CH:7]=1.[NH3:17]>C(O)C>[F:1][C:2]1[CH:3]=[C:4]([C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][C:9]=2[NH:14][C:15]([NH2:17])=[S:16])[CH:5]=[CH:6][CH:7]=1

Participants

4

Reactant 2

HCID 222AmmoniaHCID 19089300HCID 19089300, compound

Product 1

HCID 15175539HCID 15175539, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

Reaction of 3'-fluoro-2-biphenylylisothiocyanate (11.2 g) with ethanol (50 ml) with 28% aqueous ammonia solution (100 ml) for 24 hours at ambient temperature yielded N-(3'-fluoro-2-biphenylyl)thiourea (m.p. 157°-159° C.).

Sources & evidence

ORD record
ord-5d128c2e39734555b7f86bcb99153575
Source dataset
uspto-grants-1994_04
Patent number
US05302720

Reaction notes

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