Ammonia → HCID 19089272, compound

HRID 1464116Notes

Reaction equation

HRID 1464116 reaction equation
[CH3:1][O:2][C:3]1[CH:8]=[CH:7][C:6]([C:9]2[C:10]([N:15]=[C:16]=[S:17])=[CH:11][CH:12]=[CH:13][CH:14]=2)=[CH:5][CH:4]=1.[NH3:18]>C(O)C>[CH3:1][O:2][C:3]1[CH:4]=[CH:5][C:6]([C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][C:10]=2[NH:15][C:16]([NH2:18])=[S:17])=[CH:7][CH:8]=1

Participants

4

Reactant 2

HCID 222AmmoniaHCID 19089253HCID 19089253, compound

Product 1

HCID 19089272HCID 19089272, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

Reaction of 4'-methoxy-2-biphenylylisothiocyanate (12.7 g) in ethanol (30 ml) with 28% aqueous ammonia (20 ml) at 0° C. for 2 hours gave N-(4'-methoxy-2-biphenylyl)thiourea (m.p. 158°-159° C.).

Sources & evidence

ORD record
ord-135b4adb88bb4504bdf3a516c367c7f7
Source dataset
uspto-grants-1994_04
Patent number
US05302720

Reaction notes

Loading…