HuagongsheHuagongshe Chemistry Print Report · For research reference only
Allyl bromide → 1,2-dibenzyl 1-tert.butyl 4-methyl-1-(prop-2-en-1yl)-1,1,2(R)-pentanetricarboxylate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Allyl bromide | HCID 7841 | — |
| Reactant | Dibenzyl 3(RS)-tert-butoxycarbonyl-2(R)-isobutylsuccinate | HCID 18660804 | — |
| Product | 1,2-dibenzyl 1-tert.butyl 4-methyl-1-(prop-2-en-1yl)-1,1,2(R)-pentanetricarboxylate | HCID 67826212 | 91.3% |
Reaction Steps
In a manner analogous to that described in Example 45(i), from 7.28 g of 1,2-dibenzyl 1-tert.butyl 4-methyl-1,1,2(R)-pentanetricarboxylate and 3.88 g of allyl bromide there were obtained 7.234 g of 1,2-dibenzyl 1-tert.butyl 4-methyl-1-(prop-2-en-1-yl)-1,1,2(R)-pentanetricarboxylate in the form of a colorless oil; MS: 495 (M+H)+.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05304549 |
| Source dataset | uspto-grants-1994_04 |
| ORD ID | ord-2482d51bd76e435db5f23ec4866caecc |
| Source note | uspto-grants-1994_04 |