Oxalyl chloride → HCID 53674310, compound

HRID 1464761Notes

Reaction equation

HRID 1464761 reaction equation
[S:1]1[CH:5]=[CH:4][C:3]([C:6]2[CH:7]=[C:8]([CH:13]=[CH:14][CH:15]=2)[O:9][CH2:10][CH2:11][OH:12])=[CH:2]1.C(Cl)(=O)C(Cl)=O>CS(C)=O>[S:1]1[CH:5]=[CH:4][C:3]([C:6]2[CH:7]=[C:8]([CH:13]=[CH:14][CH:15]=2)[O:9][CH2:10][CH:11]=[O:12])=[CH:2]1

Participants

4

Reactant 2

HCID 65578Oxalyl chlorideHCID 19916949HCID 19916949, compound

Product 1

HCID 53674310HCID 53674310, compound

Reagents, catalysts & solvents 1

HCID 679Dimethyl SulfoxideSolvent

Procedure

The resulting alcohol compound was oxidized in a similar manner to that described in J. Org. Chem., 43, 2481 (1978) using oxalyl chloride and dimethylsulfoxide to give the captioned compound.

Workup

  1. customto give the captioned compound

Sources & evidence

ORD record
ord-43a447ec90a0462d82c96de3967e78ea
Source dataset
uspto-grants-1994_04
Patent number
US05306728

Reaction notes

Loading…