Diethylamine → HCID 86664946, compound

HRID 1468204Notes

Reaction equation

HRID 1468204 reaction equation
[CH:1]([O:3][CH2:4][F:5])=[O:2].[CH2:6]([NH:8][CH2:9][CH3:10])[CH3:7]>>[CH2:6]([N:8]([CH2:9][CH3:10])[C:1](=[O:2])[O:3][CH2:4][F:5])[CH3:7]

Participants

3

Reactant 2

HCID 8021DiethylamineHCID 12520239HCID 12520239, compound

Product 1

HCID 86664946HCID 86664946, compound

Procedure

In a 100 mL PFA-flask, fluoromethyl formate (27.0 g, 245 mmol) is given. Diethylamine (50.5 mL; 0.490 mmol) is added dropwise at about 0° C. The mixture is stirred for 1 hour. Solids are filtered off, and the resulting liquid is subjected to a distillation to isolate pure fluoromethyl N,N-diethylcarbamate.

Workup

  1. filtrationSolids are filtered off
  2. distillationthe resulting liquid is subjected to a distillation

Sources & evidence

ORD record
ord-f9bf730508f5421c94e7de80b48e6450
Source dataset
uspto-grants-2015_04
Patent number
US09000204B2

Reaction notes

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