HRID147078

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID175

Acetate

C2H3O2-

2 次

HCID813

Potassium cation

K+

2 次

HCID11776

Triphenylphosphine

C18H15P

HCID19660

Carbonate

CO3-2

HCID31275

1,4-Dioxane

C4H8O2

HCID105144

Palladium(2+)

Pd+2

HCID57813382

B-[3-[[[(1,1-Dimethylethyl)dimethylsilyl]oxy]methyl]phenyl]boronic acid

C13H23BO3Si

HCID57813399

未命名化合物

PRODUCTS

生成物

结构：CC(C)(C)OC(=O)NCc1cccc(-c2cccc(CO[Si](C)(C)C(C)(C)C)c2)c1F

HCID57813431

未命名化合物

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-3c61563d1f604004872607b77559f294
来源数据集: Training data from https://doi.org/10.1039/C8SC04228D (9/10)
DOI: 10.1039/C8SC04228D
来源说明: Training data from https://doi.org/10.1039/C8SC04228D (9/10)

反应 SMILES

[Br:26][c:27]1[c:28]([F:42])[c:29]([CH2:33][NH:34][C:35]([O:36][C:37]([CH3:38])([CH3:39])[CH3:40])=[O:41])[cH:30][cH:31][cH:32]1.[CH2:61]1[O:62][CH2:63][CH2:64][O:65][CH2:66]1.[CH3:43][C:44]([CH3:45])([CH3:46])[Si:47]([O:48][CH2:49][c:50]1[cH:51][c:52]([B:56]([OH:57])[OH:58])[cH:53][cH:54][cH:55]1)([CH3:59])[CH3:60].[K+:20].[K+:21].[O-:22][C:23]([O-:24])=[O:25].[O-:68][C:69]([CH3:70])=[O:71].[O-:72][C:73]([CH3:74])=[O:75].[Pd+2:67].[c:1]1([P:2]([c:3]2[cH:4][cH:5][cH:6][cH:7][cH:8]2)[c:9]2[cH:10][cH:11][cH:12][cH:13][cH:14]2)[cH:15][cH:16][cH:17][cH:18][cH:19]1>>[c:27]1(-[c:52]2[cH:51][c:50]([CH2:49][O:48][Si:47]([C:44]([CH3:43])([CH3:45])[CH3:46])([CH3:59])[CH3:60])[cH:55][cH:54][cH:53]2)[c:28]([F:42])[c:29]([CH2:33][NH:34][C:35]([O:36][C:37]([CH3:38])([CH3:39])[CH3:40])=[O:41])[cH:30][cH:31][cH:32]1