Acetic Anhydride → HCID 68725716, compound

HRID 1471407Notes

Reaction equation

HRID 1471407 reaction equation
O[CH:2]([CH3:17])[CH2:3][C:4]([C:6]1[C:7]2([CH2:12][CH:13]=[CH:14][C:15]=1[CH3:16])[CH2:11][CH2:10][CH2:9][CH2:8]2)=[O:5].C(OC(=O)C)(=O)C.C([O-])(=O)C.[Na+]>>[CH3:16][C:15]1[CH:14]=[CH:13][CH2:12][C:7]2([CH2:11][CH2:10][CH2:9][CH2:8]2)[C:6]=1[C:4](=[O:5])/[CH:3]=[CH:2]/[CH3:17]

Participants

4

Reactant 3

HCID 7918Acetic AnhydrideHCID 517045Sodium AcetateHCID 68724806HCID 68724806, compound

Product 1

HCID 68725716HCID 68725716, compoundYield 69%

Procedure

Prepared in 69% yield from 3-hydroxy-1-(7-methylspiro[4.5]deca-6,8-dien-6-yl)butan-1-one (1.88 g, 8.0 mmol), acetic anhydride (1.6 ml) and sodium acetate (0.72 g) as described in Example 10. Boiling point: 120° C. (0.09 mbar).

Sources & evidence

ORD record
ord-cc9c7d950fc441b2a6b301fd442dab42
Source dataset
uspto-grants-2015_04
Patent number
US09012391B2

Reaction notes

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