HRID1471412

反应详情

EQUATION

反应方程式

HRID 1471412 的结构方程式

AUXILIARIES

试剂、催化剂与溶剂

1

PROCEDURE

实验过程

Prepared as described in Example 10, from 1-(spiro[4.5]deca-2,6-dien-6-yl)ethanone via 3-hydroxy-1-(spiro[4.5]deca-2,6-dien-6-yl)butan-1-one (LDA, acetaldehyde, THF, 72% after FC (SiO2, hexane/MTBE 1:1); 17% starting material recovered) and subsequent Ac2O/AcONa treatment (35% after FC (SiO2, hexane/MTBE 30:1)). Boiling point: 110° C. (0.08 mbar).

WORKUP

后处理

  1. customPrepared