Tetrahydrofuran → HCID 131731271, compound

HRID 1475592Notes

Reaction equation

HRID 1475592 reaction equation
[I-:1].[Ce+3:2].[I-].[I-].[C:5]([C:9]1[N-:10][C:11]([C:19]([CH3:23])([CH3:22])[CH2:20][CH3:21])=[C:12]([C:14]([CH3:18])([CH3:17])[CH2:15][CH3:16])[N:13]=1)([CH3:8])([CH3:7])[CH3:6].[K+].[CH2:25]1[CH2:29][O:28][CH2:27][CH2:26]1>>[O:28]1[CH2:29][CH2:25][CH2:26][CH2:27]1.[O:28]1[CH2:29][CH2:25][CH2:26][CH2:27]1.[I-:1].[I-:1].[C:5]([C:9]1[N-:13][C:12]([C:14]([CH3:17])([CH3:18])[CH2:15][CH3:16])=[C:11]([C:19]([CH3:23])([CH3:22])[CH2:20][CH3:21])[N:10]=1)([CH3:8])([CH3:7])[CH3:6].[Ce+3:2]

Participants

4

Reactant 3

HCID 8028TetrahydrofuranHCID 25021391Cerium(III) iodideHCID 131731268HCID 131731268, compound

Product 1

HCID 131731271HCID 131731271, compound

Procedure

Cerium (III) iodide (2.0 g, 0.0038 mol) was stirred in 50 mL of dry THF for 30 mins at room temperature. Potassium 2-tert-butyl-4,5-di(1,1-dimethylpropyl)imidazolate (1.15 g, 0.0038 mol) was added, and the resulting mixture was refluxed for 90 hours. The solvent was removed by vacuum, followed by hexane extraction of the resulting solid. The hexane was removed by vacuum to yield the final product.

Workup

  1. temperaturethe resulting mixture was refluxed for 90 hours
  2. customThe solvent was removed by vacuum
  3. extractionfollowed by hexane extraction of the resulting solid
  4. customThe hexane was removed by vacuum

Sources & evidence

ORD record
ord-dfe6e251523a453c865a691fb7f64df2
Source dataset
uspto-grants-2015_04
Patent number
US09018387B2

Reaction notes

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