HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sodium hydride → HCID 53240984, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sodium hydride | HCID 24758 | — |
| Reactant | 2-Methanesulfonylbenzene-1-sulfonyl chloride | HCID 2735178 | — |
| Reactant | tert-Butyl benzoyloxycarbamate | HCID 10037153 | — |
| Product | HCID 53240984 | HCID 53240984 | — |
Reaction Steps
tert-Butyl {[2-(methylsulfonyl)phenyl]sulfonyl}[(phenylcarbonyl)oxy]carbamate (47) is prepared from 2-methylsulfonylbenzenesulfonyl chloride, sodium hydride and [(tert-butoxy)carbonyl]amino benzoate according to Scheme 2. (1.7 g, 91%), 1H NMR (250 MHz, DMSO-d6) δ ppm 8.25-8.45 (2H, m), 8.03-8.20 (4H, m), 7.77-7.93 (1H, m), 7.59-7.73 (2H, m), 3.48 (3H, s), 1.29 (9H, s).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09018411B2 |
| Source dataset | uspto-grants-2015_04 |
| ORD ID | ord-7f2d23720aac495c9611513e86f97743 |
| Source note | uspto-grants-2015_04 |