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HRID1475973

反应详情

EQUATION

反应方程式

HRID 1475973 的结构方程式

REACTANTS

反应物

3
结构：[H-].[Na+]
HCID24758

Sodium hydride

HNa

结构：CS(=O)(=O)c1ccccc1S(=O)(=O)Cl
HCID2735178

2-(methylsulfonyl)benzenesulfonyl chloride

C7H7ClO4S2

结构：CC(=O)ONC(=O)OCc1ccccc1
HCID10954788

benzyl (acetyloxy)carbamate

C10H11NO4

PRODUCTS

生成物

1
结构：CC(=O)ON(C(=O)OCc1ccccc1)S(=O)(=O)c1ccccc1S(C)(=O)=O
HCID53240987

未命名化合物

PROCEDURE

实验过程

Benzyl (acetyloxy){[2-(methylsulfonyl)phenyl]sulfonyl}carbamate (50) is prepared from 2-methylsulfonylbenzenesulfonyl chloride, sodium hydride and [(benzyloxy) carbonyl]amino acetate according to Scheme 2. (0.33 g, 28%), 1H NMR (500 MHz, CHLOROFORM-d) δ ppm 8.21-8.47 (2H, m), 7.79-7.88 (1H, m), 7.65-7.74 (1H, m), 7.30-7.41 (3H, m), 7.16-7.24 (2H, m), 5.18 (2H, br. s.), 3.31 (3H, s), 2.29 (3H, s).