Hydrogen Peroxide → Hexadecylphosphonic Acid

HRID 1476015Notes

Reaction equation

HRID 1476015 reaction equation
[CH2:1]([P:17]([OH:19])[OH:18])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16].[OH:20]O>O>[CH2:1]([P:17](=[O:20])([OH:19])[OH:18])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16]

Participants

4

Reactant 2

HCID 784Hydrogen PeroxideHCID 86658438Hexadecylphosphonous acid

Product 1

HCID 13783525Hexadecylphosphonic AcidYield 97%

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

29.0 g (0.1 mol) of hexadecylphosphonous acid (produced as in example 7) are suspended in 150 ml of water and at about 30° C. 30% strength hydrogen peroxide solution is passed through the suspension at a flow rate of 1 mol equivalent per hour. After the reaction has ended after 6 hours, the reaction solution is filtered and the residue is dried under reduced pressure to obtain 29.7 g (97% of theory) of hexadecylphosphonic acid as a colorless solid.

Workup

  1. filtrationthe reaction solution is filtered
  2. customthe residue is dried under reduced pressure

Sources & evidence

ORD record
ord-9e94add95cfd4eb88c6d8dd8ed081360
Source dataset
uspto-grants-2015_04
Patent number
US09018413B2

Reaction notes

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