HCID 136471032, compound → HCID 122443720, compound

HRID 1479934Notes

Reaction equation

HRID 1479934 reaction equation
[C:1]1([C:7]2[N:12]=[C:11]([C:13]3[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=3)[N:10]=[C:9]([C:19]3[CH:32]=[CH:31][C:30]4[C:21](=[C:22]([C:44]5[CH:53]=[CH:52][C:51]([OH:54])=[C:50]6[C:45]=5[CH:46]=[CH:47][CH:48]=[N:49]6)[C:23]5[C:28]([C:29]=4[C:33]4[CH:42]=[CH:41][C:40]([OH:43])=[C:39]6[C:34]=4[CH:35]=[CH:36][CH:37]=[N:38]6)=[CH:27][CH:26]=[CH:25][CH:24]=5)[CH:20]=3)[N:8]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.C([Li:59])CCC>C(#N)C>[C:13]1([C:11]2[N:12]=[C:7]([C:1]3[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=3)[N:8]=[C:9]([C:19]3[CH:32]=[CH:31][C:30]4[C:21](=[C:22]([C:44]5[CH:53]=[CH:52][C:51]([O-:54])=[C:50]6[C:45]=5[CH:46]=[CH:47][CH:48]=[N:49]6)[C:23]5[C:28]([C:29]=4[C:33]4[CH:42]=[CH:41][C:40]([O-:43])=[C:39]6[C:34]=4[CH:35]=[CH:36][CH:37]=[N:38]6)=[CH:27][CH:26]=[CH:25][CH:24]=5)[CH:20]=3)[N:10]=2)[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1.[Li+:59].[Li+:59]

Participants

4

Reactant 2

HCID 136471032HCID 136471032, compoundHCID 178418339Butyllithium

Product 1

HCID 122443720HCID 122443720, compound

Reagents, catalysts & solvents 1

HCID 6342AcetonitrileSolvent

Procedure

5,5′-[2-(4,6-Diphenyl-1,3,5-triazinyl)anthracene-9,10-diyl)bisquinolin-8-ol (6.95 g, 10 mmol) is dissolved in acetonitrile (300 ml), and 2.5 M n-butyl-lithium (9.9 ml, 25 mmol) is added. The solution is stirred at room temperature for 1 h. The yellow precipitate is filtered off, washed with acetonitrile and dried in vacuo (5.8 g, 80%).

Workup

  1. filtrationThe yellow precipitate is filtered off
  2. washwashed with acetonitrile
  3. customdried in vacuo (5.8 g, 80%)

Sources & evidence

ORD record
ord-5410277e3e924d40a8055da244913982
Source dataset
uspto-grants-2016_08
Patent number
US09409883B2

Reaction notes

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