Potassium Cation → Diethyl 5-oxoazepane-1,4-dicarboxylate

HRID 148308Notes

Reaction equation

HRID 148308 reaction equation
[C:21](=[O:22])([O-:23])[O-:24].[CH2:9]([CH3:10])[O:11][C:12](=[O:13])[N:14]1[CH2:15][CH2:16][C:17](=[O:20])[CH2:18][CH2:19]1.[CH3:27][CH2:28][O:29][CH2:30][CH3:31].[K+:25].[K+:26].[N+:1](=[N-:2])=[CH:3][C:4](=[O:5])[O:6][CH2:7][CH3:8]>>[CH:3]1([C:4](=[O:5])[O:6][CH2:7][CH3:8])[C:17](=[O:20])[CH2:16][CH2:15][N:14]([C:12]([O:11][CH2:9][CH3:10])=[O:13])[CH2:19][CH2:18]1

Participants

6

Reactant 5

HCID 813Potassium Cation2×HCID 3283Diethyl EtherHCID 12192Ethyl diazoacetateHCID 19660Carbonate IonHCID 34767Ethyl 4-oxo-1-piperidinecarboxylate

Product 1

HCID 12485293Diethyl 5-oxoazepane-1,4-dicarboxylate

Sources & evidence

ORD record
ord-f9edebac67eb4d7dabddac8408418101
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (9/10)

Reaction notes

Loading…