反应详情

To a solution in diethyl ether (12.0 mL) of the ethyl cis-2-phenylcyclopropanecarboxylate (1.51 g) obtained in step (1) above, a suspension of aluminum lithium hydride (393 mg) in diethyl ether (12.0 mL) was added at 0° C. After being brought to room temperature, the mixture was stirred for 2 hours. After adding sodium sulfate decahydrate at 0° C., the reaction mixture was brought to room temperature and stirred for an hour. After removing the insoluble matter by filtration, the filtrate was concentrated under reduced pressure to give (cis-2-phenylcyclopropyl)methanol as a colorless oil (1.21 g).

1. additionwas added at 0° C
2. customAfter being brought to room temperature
3. customwas brought to room temperature
4. stirringstirred for an hour
5. customAfter removing the insoluble matter
6. filtrationby filtration
7. concentrationthe filtrate was concentrated under reduced pressure