Methyl Acrylate → HCID 18674570, compound

HRID 1488919Notes

Reaction equation

[C:1]([O:5][CH3:6])(=[O:4])[CH:2]=[CH2:3].[C:7]([O:12][CH2:13][CH:14]1[O:16][CH2:15]1)(=[O:11])[C:8]([CH3:10])=[CH2:9]>>[C:1]([O:5][CH3:6])(=[O:4])[CH:2]=[CH2:3].[CH2:13]([O:12][C:7](=[O:11])[C:8]([CH3:10])=[CH2:9])[CH:14]1[O:16][CH2:15]1

Participants

Reactant 2

HCID 7294Methyl Acrylate

HCID 7837Glycidyl methacrylate

Product 1

HCID 18674570HCID 18674570, compound

Procedure

Using methyl acrylate (21.5 g, 0.25 mole) and glycidyl methacrylate (14.2 g, 0.10 mole), the polymerization was carried out in the same manner as described in Synthesis Example 12, (1). The precipitate was filtered and dried under reduced pressure to give 21.0 g of poly(methyl acrylate/glycidylmethacrylate) as a colorless viscous oil having Mw 35000 and Mn 18000 (GPC with polystyrene calibration). The composition of the polymer was found to be methyl acrylate unit and glycidyl methacrylate unit in molar ratio of ca. 5:2 based on 1HNMR analysis.

Workup

filtrationThe precipitate was filtered
customdried under reduced pressure

Sources & evidence

ORD record: ord-d52383851c7b40249679267e5931c912
Source dataset: uspto-grants-1997_10
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05677112

Reaction notes

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