HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1490501Generated: October 30, 2026
HCID 12735200, compound → HCID 178422404, compound
https://huagongshe.com/reaction/1490501
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | HCID 12735200 | HCID 12735200 | — |
| Reagent | Pinacol | HCID 6425 | — |
| Reagent | Triethylamine | HCID 8471 | — |
| Reagent | Catecholborane | HCID 67506 | — |
| Catalyst | Tris(pentafluorophenyl)borane | HCID 582056 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | HCID 178422404 | HCID 178422404 | 75% |
Reaction Steps
Prepared from 1,8-dimethyl-1,2,3,4-tetrahydroquinoline (1l, 32.2 mg, 0.200 mmol, 1.00 equiv) and catBH (36.0 mg, 0.300 mmol, 1.50 equiv) according to GP 1. The title compound was purified by flash column chromatography using cyclohexane/EtOAc/Et3N (30/1/1) as eluent to afford 3l (43.1 mg, 75%) as a white solid
Provenance & Evidence
| DOI | 10.1002/anie.201611536 |
|---|
| Source dataset | Borylation dataset from Roche |
|---|
| ORD ID | ord-a5383b6d58804592a987d6287c524a14 |
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| Source note | Borylation dataset from Roche |
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