HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1490702Generated: October 31, 2026
4-Cyanophenol → 4-Methoxy-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzonitrile
https://huagongshe.com/reaction/1490702
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | 4-Cyanophenol | HCID 13019 | — |
| Reagent | Bis(pinacolato)diborane | HCID 2733548 | — |
| Reagent | 4,4,5,5-Tetramethyl[1,3,2]dioxaborolane | HCID 2734768 | — |
| Reagent | 4,4'-Di-tert-butyl-2,2'-bipyridyl | HCID 4249187 | — |
| Catalyst | Bis(1,5-cyclooctadiene)dimethoxydiiridium | HCID 76001521 | — |
| Solvent | Cyclohexane | HCID 8078 | — |
| Product | 4-Methoxy-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzonitrile | HCID 46739734 | 21% |
| Product | 4-Methoxy-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzonitrile | HCID 59764021 | 44% |
Provenance & Evidence
| DOI | 10.1021/jacs.7b02232 |
|---|
| Source dataset | Borylation dataset from Roche |
|---|
| ORD ID | ord-95200908db9e43dda4e01a8ca181a292 |
|---|
| Source note | Borylation dataset from Roche |
|---|
