Phosphine oxide, dicyclohexylphenyl- → Dicyclohexyl(3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)phosphine oxide

HRID 1490898Notes

Reaction equation

HRID 1490898 reaction equation
O=P(c1ccccc1)(C1CCCCC1)C1CCCCC1>C1=CCCC=CCC1.C1=CCCC=CCC1.CC(C)(C)c1ccnc(-c2cc(C(C)(C)C)ccn2)c1.CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C.C[OH2+].C[OH2+].Cc1ccc(C)cc1.[Ir].[Ir]>CC1(C)OB(c2cccc(P(=O)(C3CCCCC3)C3CCCCC3)c2)OC1(C)C

Participants

6

Reactant 1

HCID 610285Phosphine oxide, dicyclohexylphenyl-

Product 1

HCID 91820770Dicyclohexyl(3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)phosphine oxideYield 35%

Reagents, catalysts & solvents 4

HCID 2733548Bis(pinacolato)diboraneReagentHCID 42491874,4'-Di-tert-butyl-2,2'-bipyridylReagentHCID 76001521Bis(1,5-cyclooctadiene)dimethoxydiiridiumCatalystHCID 7809P-XyleneSolvent

Conditions

Temperature
40 °C

Sources & evidence

ORD record
ord-95953f816edc4f44bd66ab8113a95138
Source dataset
Borylation dataset from Roche

Reaction notes

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