HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1491048Generated: October 31, 2026
HCID 4298049, compound → HCID 178431002, compound
https://huagongshe.com/reaction/1491048
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | HCID 4298049 | HCID 4298049 | — |
| Reagent | 3,4,7,8-Tetramethyl-1,10-phenanthroline | HCID 74265 | — |
| Reagent | 4,4,5,5-Tetramethyl[1,3,2]dioxaborolane | HCID 2734768 | — |
| Catalyst | Bis(1,5-cyclooctadiene)dimethoxydiiridium | HCID 76001521 | — |
| Solvent | Cyclohexane | HCID 8078 | — |
| Product | HCID 178431002 | HCID 178431002 | 12% |
Reaction Steps
1e (200 mg, 1.3 mmol) and HBpin (0.28 mL, 2.0 mmol) were used. Purification was performed by MPLC (chloroform/acetone = 1:0 to 19:1) to afford a mixture of 1e and 2e (NMR yield 12%). The mixture was purified again by MPLC (hexane/ether = 7:3 to 1:1) to afford 2e as a colorless oil.
Provenance & Evidence
| DOI | 10.1002/anie.201409186 |
|---|
| Source dataset | Borylation dataset from Roche |
|---|
| ORD ID | ord-9e0752f7a4634dd387aa2ea8be7655a9 |
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| Source note | Borylation dataset from Roche |
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