HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1491143Generated: October 26, 2026
N,N-Dimethyl-3-(methylsulfanyl)aniline → HCID 178503074, compound
https://huagongshe.com/reaction/1491143
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | N,N-Dimethyl-3-(methylsulfanyl)aniline | HCID 20403482 | — |
| Reagent | 4,4'-Dimethyl-2,2'-bipyridine | HCID 14338 | — |
| Reagent | Bis(pinacolato)diborane | HCID 2733548 | — |
| Catalyst | Bis(1,5-cyclooctadiene)dimethoxydiiridium | HCID 76001521 | — |
| Solvent | P-Xylene | HCID 7809 | — |
| Product | HCID 178503074 | HCID 178503074 | 63% |
Reaction Steps
dtbpy: A mixture of ortho- and meta-borylated products (92 mg, 63% yield, ortho/meta + para = <0.01); meta-Isomer (5h) were obtained by further purification by GPC (88 mg, 60% yield), yellow solid;
Provenance & Evidence
| DOI | 10.1002/anie.201610041 |
|---|
| Source dataset | Borylation dataset from Roche |
|---|
| ORD ID | ord-cbd110ca6fe34a4493b2b9b6dfbb496c |
|---|
| Source note | Borylation dataset from Roche |
|---|
