N,N-dimethyl-m-toluidine → HCID 102111590, compound

HRID 1491275Notes

Reaction equation

HRID 1491275 reaction equation
Cc1cccc(N(C)C)c1>C1=CCCC=CCC1.C1=CCCC=CCC1.C1CCOC1.C1CCc2c(c3c(c4c2CCCC4)CCCC3)C1.CC1(C)OBOC1(C)C.C[OH2+].C[OH2+].Cc1cnc2c(ccc3c(C)c(C)cnc32)c1C.[Ir].[Ir]>Cc1cc(B2OC(C)(C)C(C)(C)O2)cc(N(C)C)c1

Participants

7

Reactant 1

HCID 8488N,N-dimethyl-m-toluidine

Product 1

HCID 102111590HCID 102111590, compoundYield 56%

Reagents, catalysts & solvents 5

HCID 742653,4,7,8-Tetramethyl-1,10-phenanthrolineReagentHCID 95278DodecahydrotriphenyleneReagentHCID 27347684,4,5,5-Tetramethyl[1,3,2]dioxaborolaneReagentHCID 76001521Bis(1,5-cyclooctadiene)dimethoxydiiridiumCatalystHCID 8028TetrahydrofuranSolvent

Conditions

Temperature
80 °C

Sources & evidence

ORD record
ord-44567daab2914bf0b0e5312a33149ade
Source dataset
Borylation dataset from Roche

Reaction notes

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