N,N-dimethyl-m-toluidine → HCID 102111590, compound

HRID 1491323Notes

Reaction equation

HRID 1491323 reaction equation
Cc1cccc(N(C)C)c1>C1=CCCC=CCC1.C1=CCCC=CCC1.C1CCOC1.C1CCc2c(c3c(c4c2CCCC4)CCCC3)C1.CC1(C)OBOC1(C)C.[Cl-].[Cl-].[Ir].[Ir].c1ccc(P(c2ccccc2)c2ccccc2P(c2ccccc2)c2ccccc2)cc1>Cc1cc(B2OC(C)(C)C(C)(C)O2)cc(N(C)C)c1

Participants

7

Reactant 1

HCID 8488N,N-dimethyl-m-toluidine

Product 1

HCID 102111590HCID 102111590, compoundYield 10%

Reagents, catalysts & solvents 5

HCID 95278DodecahydrotriphenyleneReagentHCID 4983791,2-Bis(diphenylphosphino)benzeneReagentHCID 27347684,4,5,5-Tetramethyl[1,3,2]dioxaborolaneReagentHCID 82923Chloro-1,5-cyclooctadiene-iridium(I) dimerCatalystHCID 8028TetrahydrofuranSolvent

Conditions

Temperature
80 °C

Sources & evidence

ORD record
ord-5eb198a404a54a56843e18d7b71f1f7e
Source dataset
Borylation dataset from Roche

Reaction notes

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