1,3-Dimethoxybenzene → 2-(3,5-Dimethoxyphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

HRID 1491396Notes

Reaction equation

HRID 1491396 reaction equation
COc1cccc(OC)c1>C1=CCCC=CCC1.C1=CCCC=CCC1.C1CCc2c(c3c(c4c2CCCC4)CCCC3)C1.CC(C)(C)c1ccnc(-c2cc(C(C)(C)C)ccn2)c1.CC1(C)OBOC1(C)C.CN1CCCC1=O.C[OH2+].C[OH2+].[Ir].[Ir]>COc1cc(OC)cc(B2OC(C)(C)C(C)(C)O2)c1

Participants

7

Reactant 1

HCID 90251,3-Dimethoxybenzene

Product 1

HCID 162176602-(3,5-Dimethoxyphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolaneYield 47%

Reagents, catalysts & solvents 5

HCID 95278DodecahydrotriphenyleneReagentHCID 27347684,4,5,5-Tetramethyl[1,3,2]dioxaborolaneReagentHCID 42491874,4'-Di-tert-butyl-2,2'-bipyridylReagentHCID 76001521Bis(1,5-cyclooctadiene)dimethoxydiiridiumCatalystHCID 13387N-methyl-2-pyrrolidoneSolvent

Conditions

Temperature
80 °C

Sources & evidence

ORD record
ord-6c55088356b3439997aff37d16642222
Source dataset
Borylation dataset from Roche

Reaction notes

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