HCID 15271993, compound → HCID 178498905, compound

HRID 1491445Notes

Reaction equation

HRID 1491445 reaction equation
COC(=O)c1cn([Si](C(C)C)(C(C)C)C(C)C)c2ccccc12>C1=CCCC=CCC1.C1=CCCC=CCC1.CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C.CC1(C)OBOC1(C)C.CCCCCC.CCCCOC(=O)c1ccnc(-c2cc(C(=O)OCCCC)ccn2)c1.C[OH2+].C[OH2+].[Ir].[Ir]>COC(=O)c1cn([Si](C(C)C)(C(C)C)C(C)C)c2cc(B3OC(C)(C)C(C)(C)O3)ccc12.COC(=O)c1cn([Si](C(C)C)(C(C)C)C(C)C)c2ccc(B3OC(C)(C)C(C)(C)O3)cc12

Participants

8

Reactant 1

HCID 15271993HCID 15271993, compound

Product 2

HCID 178498905HCID 178498905, compoundYield 58%HCID 178498906HCID 178498906, compoundYield 19%

Reagents, catalysts & solvents 5

HCID 2733548Bis(pinacolato)diboraneReagentHCID 27347684,4,5,5-Tetramethyl[1,3,2]dioxaborolaneReagentHCID 10665958HCID 10665958, compoundReagentHCID 76001521Bis(1,5-cyclooctadiene)dimethoxydiiridiumCatalystHCID 8058HexaneSolvent

Conditions

Temperature
80 °C

Sources & evidence

ORD record
ord-bcfcd4ad853a40a1831245e607f183ea
Source dataset
Borylation dataset from Roche

Reaction notes

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