HCID 122204569, compound → HCID 178435465, compound

HRID 1491446Notes

Reaction equation

HRID 1491446 reaction equation
CCc1ccc2c(c1)c1ccccc1n2[Si](C(C)C)(C(C)C)C(C)C>C1=CCCC=CCC1.C1=CCCC=CCC1.CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C.CC1(C)OBOC1(C)C.CCCCCC.C[OH2+].C[OH2+].[Ir].[Ir].c1cnc2c(c1)ccc1cccnc12>CCc1ccc2c(c1)c1cc(B3OC(C)(C)C(C)(C)O3)ccc1n2[Si](C(C)C)(C(C)C)C(C)C.CCc1ccc2c(c1)c1ccc(B3OC(C)(C)C(C)(C)O3)cc1n2[Si](C(C)C)(C(C)C)C(C)C

Participants

8

Reactant 1

HCID 122204569HCID 122204569, compound

Product 2

HCID 178435464HCID 178435464, compoundYield 14%HCID 178435465HCID 178435465, compoundYield 75%

Reagents, catalysts & solvents 5

HCID 13181,10-PhenanthrolineReagentHCID 2733548Bis(pinacolato)diboraneReagentHCID 27347684,4,5,5-Tetramethyl[1,3,2]dioxaborolaneReagentHCID 76001521Bis(1,5-cyclooctadiene)dimethoxydiiridiumCatalystHCID 8058HexaneSolvent

Conditions

Temperature
80 °C

Sources & evidence

ORD record
ord-75653b72ccbb46c0b31482d8b830df5a
Source dataset
Borylation dataset from Roche

Reaction notes

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