HCID 56697249, compound → HCID 178460904, compound

HRID 1491456Notes

Reaction equation

HRID 1491456 reaction equation
CC(C)[Si](C(C)C)(C(C)C)n1c2c(c3ccccc31)CCC2>C1=CCCC=CCC1.C1=CCCC=CCC1.CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C.CC1(C)OBOC1(C)C.CCCCCC.CCCCOC(=O)c1ccnc(-c2cc(C(=O)OCCCC)ccn2)c1.C[OH2+].C[OH2+].[Ir].[Ir]>CC(C)[Si](C(C)C)(C(C)C)n1c2c(c3cc(B4OC(C)(C)C(C)(C)O4)ccc31)CCC2.CC(C)[Si](C(C)C)(C(C)C)n1c2c(c3ccc(B4OC(C)(C)C(C)(C)O4)cc31)CCC2

Participants

8

Reactant 1

HCID 56697249HCID 56697249, compound

Product 2

HCID 178460903HCID 178460903, compoundYield 26%HCID 178460904HCID 178460904, compoundYield 40%

Reagents, catalysts & solvents 5

HCID 2733548Bis(pinacolato)diboraneReagentHCID 27347684,4,5,5-Tetramethyl[1,3,2]dioxaborolaneReagentHCID 10665958HCID 10665958, compoundReagentHCID 76001521Bis(1,5-cyclooctadiene)dimethoxydiiridiumCatalystHCID 8058HexaneSolvent

Conditions

Temperature
80 °C

Sources & evidence

ORD record
ord-c0f7fb32abca4ed3b181b95c69804ab6
Source dataset
Borylation dataset from Roche

Reaction notes

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