HCID 102362715, compound → HCID 178460909, compound

HRID 1491457Notes

Reaction equation

HRID 1491457 reaction equation
CC(C)[Si](C(C)C)(C(C)C)n1cc(C#N)c2ccccc21>C1=CCCC=CCC1.C1=CCCC=CCC1.CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C.CC1(C)OBOC1(C)C.CCCCCC.C[OH2+].C[OH2+].[Ir].[Ir].c1cnc2c(c1)ccc1cccnc12>CC(C)[Si](C(C)C)(C(C)C)n1cc(C#N)c2cc(B3OC(C)(C)C(C)(C)O3)ccc21.CC(C)[Si](C(C)C)(C(C)C)n1cc(C#N)c2ccc(B3OC(C)(C)C(C)(C)O3)cc21

Participants

8

Reactant 1

HCID 102362715HCID 102362715, compound

Product 2

HCID 178460908HCID 178460908, compoundYield 6%HCID 178460909HCID 178460909, compoundYield 48%

Reagents, catalysts & solvents 5

HCID 13181,10-PhenanthrolineReagentHCID 2733548Bis(pinacolato)diboraneReagentHCID 27347684,4,5,5-Tetramethyl[1,3,2]dioxaborolaneReagentHCID 76001521Bis(1,5-cyclooctadiene)dimethoxydiiridiumCatalystHCID 8058HexaneSolvent

Conditions

Temperature
50 °C

Sources & evidence

ORD record
ord-6cfbdd3fe91f43088fb79b5e9c2890ff
Source dataset
Borylation dataset from Roche

Reaction notes

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