Methacrylic Acid → HCID 86744813, compound

HRID 1493116Notes

Reaction equation

HRID 1493116 reaction equation
C[O-].[Ca+2:3].C[O-].[C:6]([OH:11])(=[O:10])[C:7]([CH3:9])=[CH2:8].[C:12]([OH:31])(=[O:30])[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19]/[CH:20]=[CH:21]\[CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29]>O1CCCC1>[C:6]([O-:11])(=[O:10])[C:7]([CH3:9])=[CH2:8].[C:12]([O-:31])(=[O:30])[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19]/[CH:20]=[CH:21]\[CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29].[Ca+2:3]

Participants

5

Reactant 3

HCID 4093Methacrylic AcidHCID 164985Calcium dimethanolateHCID 445639Oleic Acid

Product 1

HCID 86744813HCID 86744813, compound

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

1.02 Grams of calcium (II) methoxide (0.01 mol) was weighed in a round bottom flask in a dry box. A mixture of 0.875 g of (0.01 mol) of methacrylic acid and 2.930 g (0.01 mol) of oleic acid was mixed in 19 g of dry tetrahydrofuran. This acid-mixture was introduced into a round bottom flask which was purged with argon. The contents were magnetically stirred overnight (20 hr) at ambient temperature. The volatile matter was then removed in vacuo (0.1 mm Hg) for 10 hours at room temperature. The resulting solid was analyzed for its metal content.

Workup

  1. additionThis acid-mixture was introduced into a round bottom flask which
  2. customwas purged with argon
  3. custom(20 hr)
  4. customat ambient temperature
  5. customThe volatile matter was then removed in vacuo (0.1 mm Hg) for 10 hours at room temperature

Sources & evidence

ORD record
ord-9c10b46128b84136955778593e0df2dc
Source dataset
uspto-grants-1991_06
Patent number
US05021398

Reaction notes

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