Aluminium lithium hydride → HCID 19831112, compound

HRID 1493227Notes

Reaction equation

HRID 1493227 reaction equation
C([O:5][C:6]([C:8]1[S:9][C:10]([CH:13]([N:17]2[CH:21]=[CH:20][N:19]=[CH:18]2)[CH2:14][CH2:15][CH3:16])=[CH:11][CH:12]=1)=O)CCC.[H-].[Al+3].[Li+].[H-].[H-].[H-]>O1CCCC1>[N:17]1([CH:13]([C:10]2[S:9][C:8]([CH2:6][OH:5])=[CH:12][CH:11]=2)[CH2:14][CH2:15][CH3:16])[CH:21]=[CH:20][N:19]=[CH:18]1

Participants

4

Reactant 2

HCID 21226445Aluminium lithium hydrideHCID 54546985HCID 54546985, compound

Product 1

HCID 19831112HCID 19831112, compoundYield 129.7%

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

0.2 g of the butyl ester of example 7 is reduced in 3 ml of tetrahydrofuran with 0.2 g of lithium aluminum hydride and worked up in the usual way. 0.2 g of the title compound is obtained as oil.

Sources & evidence

ORD record
ord-79eb48e22b18429ba92f458343dff8b9
Source dataset
uspto-grants-1991_06
Patent number
US05021434

Reaction notes

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