Acetone → HCID 54274397, compound

HRID 1493428Notes

Reaction equation

HRID 1493428 reaction equation
[C:1]1(OC)[C:2](=[CH:4][CH:5]=[C:6]([CH:10]=1)[CH:7]=[CH:8][CH3:9])[OH:3].[C:13](=[O:16])([O-])[O-].[K+].[K+].[CH3:19][C:20]([CH3:22])=O>>[CH2:22]([O:3][C:2]1[CH:1]=[CH:10][C:6]([CH:7]=[CH:8][CH2:9][O:16][CH3:13])=[CH:5][CH:4]=1)[CH:20]=[CH2:19]

Participants

4

Reactant 3

HCID 180AcetoneHCID 7338IsoeugenolHCID 11430Potassium Carbonate

Product 1

HCID 54274397HCID 54274397, compound

Procedure

4-allyloxy-3-methoxypropenylbenzene was prepared by refluxing a stirred mixture of isoeugenol (164 g),allybromide (133 g) and potassium carbonate (278 g) in dry acetone (700 mls) for 18 hours. Removal of the solids and solvent gave a crude product 208 g which was vacuum distilled to yield 130 g of pure 4-allyloxy-3-methoxy-prop-1-enylbenzene (b.p.. 104-118° C. at 0.1 imbar).

Workup

  1. temperatureby refluxing
  2. customRemoval of the solids and solvent
  3. customgave a crude product 208 g which

Sources & evidence

ORD record
ord-4f3efa7a70334a0e939489917ab77cae
Source dataset
uspto-grants-1991_06
Patent number
US05021512

Reaction notes

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