HuagongsheHuagongshe Chemistry Print Report · For research reference only
Tert-Butylamine → HCID 14851222, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Tert-Butylamine | HCID 6385 | — |
| Reactant | Bromine | HCID 24408 | — |
| Reactant | 3-Hydroxy-4-nitrobenzoic acid | HCID 69265 | — |
| Product | HCID 14851222 | HCID 14851222 | 70.1% |
Reaction Steps
A 0.1 mole of the ethyl ester of 3-hydroxy-4-nitrobenzoic acid was monobrominated using the procedure described in Example 1, except only one equivalent of bromine and two equivalents of t-butyl amine were used. This reaction yielded ethyl 2-bromo-3-hydroxy-4-nitrobenzoate in 70.1% yield. It had a melting point of 58°-61° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05026896 |
| Source dataset | uspto-grants-1991_06 |
| ORD ID | ord-f1999c3815574bde871143fa1f1b8bb8 |
| Source note | uspto-grants-1991_06 |