Perfluorotetradecahydrophenanthrene → Phenanthrene, decafluoro-

HRID 1494711Notes

Reaction equation

[F:1][C:2]1(F)[C:15]2(F)[C:6](F)([C:7]3(F)[C:12](F)([C:13](F)([F:19])[C:14]2(F)[F:17])[C:11](F)([F:22])[C:10](F)([F:24])[C:9](F)([F:26])[C:8]3(F)[F:28])[C:5](F)([F:32])[C:4](F)([F:34])[C:3]1(F)[F:36].[Na]>>[F:17][C:14]1[C:15]2[C:2]([F:1])=[C:3]([F:36])[C:4]([F:34])=[C:5]([F:32])[C:6]=2[C:7]2[C:12](=[C:11]([F:22])[C:10]([F:24])=[C:9]([F:26])[C:8]=2[F:28])[C:13]=1[F:19]

Participants

Reactant 2

HCID 78972Perfluorotetradecahydrophenanthrene

HCID 5360545Sodium

Product 1

HCID 123121Phenanthrene, decafluoro-

Procedure

The products from 3 reactions were analyzed by gas chromatography and for each of these reactions for which an excess of perfluoroperhydrophenanthrene (0.39 mmol) and 3.38 mmol sodium was used, yields of decafluorophenanthrene (based on sodium) ranged from 40-56%.

Sources & evidence

ORD record: ord-fbb4881d91ae4840a5845a0935896dd1
Source dataset: uspto-grants-1991_06
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05026929

Reaction notes

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