2-Chlorophenol → 2,4,6-Trichlorophenol

HRID 1494712Notes

Reaction equation

[Cl:1]C1C=CC=CC=1O.[Cl:9][C:10]1[CH:15]=[C:14]([Cl:16])[CH:13]=[CH:12][C:11]=1[OH:17]>>[Cl:9][C:10]1[CH:15]=[C:14]([Cl:16])[CH:13]=[C:12]([Cl:1])[C:11]=1[OH:17]

Participants

Reactant 2

HCID 72452-Chlorophenol

HCID 84492,4-Dichlorophenol

Product 1

HCID 69142,4,6-Trichlorophenol

Procedure

The chlorination was continued for 12 minutes until the ortho-chlorophenol and 2,4-dichlorophenol had almost completely disappeared (less than 0.2% in the mixture).

Sources & evidence

ORD record: ord-d478e97fc78f480c8fd37d34eeb3ea57
Source dataset: uspto-grants-1991_06
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05026926

Reaction notes

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