Acetonitrile → HCID 86714716, compound

HRID 1500135Notes

Reaction equation

HRID 1500135 reaction equation
[CH2:1]([Br:4])[CH:2]=C.[CH:5](/[N:9]([CH2:14][CH:15]([CH3:17])[CH3:16])[CH2:10][CH:11]([CH3:13])[CH3:12])=[CH:6]\[CH2:7][CH3:8].[C:18](#N)C>>[Br-:4].[CH2:10]([N+:9]([CH2:14][CH:15]([CH3:16])[CH3:17])=[CH:5][CH:6]([CH2:1][CH3:2])[CH2:7][CH:8]=[CH2:18])[CH:11]([CH3:12])[CH3:13]

Participants

4

Reactant 3

HCID 6342AcetonitrileHCID 7841Allyl bromideHCID 86714715HCID 86714715, compound

Product 1

HCID 86714716HCID 86714716, compoundYield 92%

Conditions

Temperature
60 °C

Procedure

Allyl bromide (1.30 mL, 15 mmol) was added to a mixture of (E)-but-1-enyldiisobutylamine (1.83 g, 10 mmol) and acetonitrile (5.5 mL) at room temperature under a nitrogen atmosphere, and the mixture was then stirred at an external temperature of 60° C. for 15 hours. The reaction mixture was cooled to room temperature and then concentrated under reduced pressure to obtain the title compound (2.79 g, 92%) as a red purple solid.

Workup

  1. temperatureThe reaction mixture was cooled to room temperature
  2. concentrationconcentrated under reduced pressure

Sources & evidence

ORD record
ord-4c8fe62e050845f6bc7cdde7866ffce2
Source dataset
uspto-grants-2015_12
Patent number
US09206104B2

Reaction notes

Loading…