Propanal → HCID 58500190, compound

HRID 1500170Notes

Reaction equation

HRID 1500170 reaction equation
[N+:1](/[CH:4]=[CH:5]/[CH:6]1[CH2:11][CH2:10][CH2:9][CH2:8][CH2:7]1)([O-:3])=[O:2].[CH:12](=[O:15])[CH2:13][CH3:14].CC(O)C>CCCCCC>[CH:6]1([C@H:5]([CH2:4][N+:1]([O-:3])=[O:2])[C@H:13]([CH3:14])[CH:12]=[O:15])[CH2:11][CH2:10][CH2:9][CH2:8][CH2:7]1

Participants

5

Reactant 3

HCID 527PropanalHCID 3776IsopropanolHCID 11094860132839-80-6

Product 1

HCID 58500190HCID 58500190, compound

Reagents, catalysts & solvents 1

HCID 8058HexaneSolvent

Procedure

The title compound was prepared from (E)-(2-nitrovinyl)cyclohexane and propionaldehyde according to general procedure. The enantiomeric excess was determined by HPLC with Chiralpak AD-H column at 210 nm (2-propanol:hexane=1:99), 1 mL/min, tmajor=17.0 min, tminor=19.1 min, the diastereomeric ratio was determined by

Sources & evidence

ORD record
ord-76c589482c8b41ef9d406608fb1e19ad
Source dataset
uspto-grants-2015_12
Patent number
US09206090B2

Reaction notes

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