化工社化工社 化学情報印刷レポート · 研究参考用
Water → 1-(Allyloxy)-4-methyl-2-nitrobenzene
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Water | HCID 962 | — |
| 反応物 | Allyl bromide | HCID 7841 | — |
| 反応物 | 4-Methyl-2-nitrophenol | HCID 8391 | — |
| 反応物 | Potassium Carbonate | HCID 11430 | — |
| 溶媒 | Acetone | HCID 180 | — |
| 生成物 | 1-(Allyloxy)-4-methyl-2-nitrobenzene | HCID 21075357 | — |
反応手順
A mixture of 4-methyl-2-nitrophenol (5.0 g, 0.033 mol), 3-bromoprop-1-ene (4.2 g, 0.034 mol) and K2CO3 (4.6 g, 0.033 mol) in acetone (20 mL) was stirred for 8 h at ambient temperature. The mixture was poured into water (50 mL), extracted with EtOAc (90 mL), washed with brine, dried and concentrated to give the title compound (7a).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US09206166B2 |
| 出典データセット | uspto-grants-2015_12 |
| ORD ID | ord-e9d414ef53804be9ad7bc425ba6670d4 |
| 出典メモ | uspto-grants-2015_12 |