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HRID1502227

反应详情

EQUATION

反应方程式

HRID 1502227 的结构方程式

REACTANTS

反应物

2
结构：CC(=O)O[C@@]12CO[C@@H]1C[C@H](O)[C@@]1(C)C(=O)[C@H](O)C3=C(C)[C@@H](O)C[C@@](O)([C@@H](OC(=O)c4ccccc4)[C@H]21)C3(C)C
HCID154272

10-Deacetylbaccatin III

C29H36O10

结构：CC(=O)O[C@@]12CO[C@@H]1C[C@H](O[C@@H]1OC[C@@H](O)[C@H](O)[C@H]1O)[C@@]1(C)C(=O)[C@H](O)C3=C(C)[C@@H](O)C[C@@](O)([C@@H](OC(=O)c4ccccc4)[C@H]21)C3(C)C
HCID5315356

未命名化合物

2 次

PRODUCTS

生成物

1
结构：CC(=O)O[C@H]1C(=O)[C@]2(C)[C@@H](O[C@@H]3OC[C@@H](O)[C@H](O)[C@H]3O)C[C@H]3OC[C@@]3(OC(C)=O)[C@H]2[C@H](OC(=O)c2ccccc2)[C@]2(O)C[C@H](O)C(C)=C1C2(C)C
HCID11672124

未命名化合物

PROCEDURE

实验过程

The strain was the same as that in Example 6 and the substrate was 7-xylosyl-10-deacetylbaccatin III (XDB). 1.5 ml cell reaction solution contained 16 mg dry cells per milliliter and 8 mg XDB per milliliter. The mixture was incubated in a water shaking bath for 24 h at 30˜55° C. HPLC analysis results showed that the conversion ratio of XDB was 86.54% and the yield of the product, 10-deacetylbaccatin III (DB), was 5.57 mg/ml (FIG. 7).

WORKUP

后处理

  1. custom1.5 ml cell reaction solution
  2. dry with materialdry cells per milliliter and 8 mg XDB per milliliter
  3. customHPLC analysis results