Methanol → Hydrogen iodide

HRID 150248Notes

Reaction equation

HRID 150248 reaction equation
[CH3:40][OH:41].[Cl:28][Si:29]([CH3:30])([CH3:31])[CH3:32].[I-:27].[N:1](=[N+:2]=[N-:3])[CH2:4][CH2:5][NH:6][c:7]1[c:8](-[c:12]2[n:13][o:14][c:15](=[O:25])[n:16]2-[c:17]2[cH:18][c:19]([Br:24])[c:20]([F:23])[cH:21][cH:22]2)[n:9][o:10][n:11]1.[Na+:26].[Na+:38].[Na+:39].[OH2:42].[S:33]([O-:34])([O-:35])(=[O:36])=[S:37]>>[IH:27].[NH2:1][CH2:4][CH2:5][NH:6][c:7]1[c:8](-[c:12]2[n:13][o:14][c:15](=[O:25])[n:16]2-[c:17]2[cH:18][c:19]([Br:24])[c:20]([F:23])[cH:21][cH:22]2)[n:9][o:10][n:11]1

Participants

9

Reactant 7

HCID 887MethanolHCID 923Sodium ion3×HCID 962WaterHCID 1084Thiosulfate ionHCID 6397ChlorotrimethylsilaneHCID 30165Iodide IonHCID 86637999HCID 86637999, compound

Product 2

HCID 24841Hydrogen iodideHCID 66605742HCID 66605742, compound

Sources & evidence

ORD record
ord-c3f27a61c510423a9103375f6ea97dd4
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (9/10)

Reaction notes

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