4-Methoxycyclohexanol (cis,trans) → HCID 178491879, compound

HRID 1504391Notes

Reaction equation

HRID 1504391 reaction equation
[I-:1].O1CCC([Zn+:8])CC1.[CH3:9][O:10][CH:11]1[CH2:16][CH2:15][CH:14](O)[CH2:13][CH2:12]1>C1COCC1>[I-:1].[CH3:9][O:10][CH:11]1[CH2:16][CH2:15][CH:14]([Zn+:8])[CH2:13][CH2:12]1

Participants

4

Reactant 2

HCID 1403324-Methoxycyclohexanol (cis,trans)HCID 178506619HCID 178506619, compound

Product 1

HCID 178491879HCID 178491879, compound

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

The title compound was prepared in an analogous manner to (tetrahydro-2H-pyran-4-yl)zinc(II) iodide except that 4-methoxycyclohexanol was used instead of tetrahydro-2H-pyran-4-ol in Step 1 to afford a 0.28M solution of (4-methoxycyclohexyl)zinc(11) iodide in THF.

Sources & evidence

ORD record
ord-eed94c8b4028465ba4cdd3d344a57611
Source dataset
uspto-grants-2015_12
Patent number
US09212182B2

Reaction notes

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