Hexane → Ethyl acetate hexane

HRID 1504563Notes

Reaction equation

HRID 1504563 reaction equation
[CH:1]1[C:2](C(F)(F)F)=[CH:3][C:4](Cl)=[C:5](N2N=C(C#N)C([S+]([O-])C(F)(F)F)=C2N)[C:6]=1Cl.CCCCCC.[C:33]([O:36][CH2:37][CH3:38])(=[O:35])[CH3:34]>>[CH3:3][CH2:2][CH2:1][CH2:6][CH2:5][CH3:4].[C:33]([O:36][CH2:37][CH3:38])(=[O:35])[CH3:34]

Participants

4

Reactant 3

HCID 8058HexaneHCID 8857Ethyl AcetateHCID 178510672HCID 178510672, compound

Product 1

HCID 21226206Ethyl acetate hexane

Procedure

Slurry of 2 g. of fipronil and 90 g. of n-hexane was heated up to 69° C. Ethyl acetate was added dropwise until a clear solution was obtained (total of 71 g.). The solution was then cooled under agitation to room temperature. White crystals obtained in the bottom of the flask. The crystals were filtered and then dried at 40° C.

Workup

  1. customwas obtained (total of 71 g.)
  2. customWhite crystals obtained in the bottom of the flask
  3. filtrationThe crystals were filtered
  4. customdried at 40° C.

Sources & evidence

ORD record
ord-328fdd68c2cc4198bafb530f2538646f
Source dataset
uspto-grants-2015_12
Patent number
US09215873B2

Reaction notes

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