6-iodo-3,4-dihydronaphthalen-1(2H)-one → (NE)-N-(6-iodo-3,4-dihydro-2H-naphthalen-1-ylidene)hydroxylamine

HRID 1506532Notes

Reaction equation

HRID 1506532 reaction equation
C(C1C=C2C(=CC=1)/C(=[N:12]/[OH:13])/CC2)=C.[I:14][C:15]1[CH:16]=[C:17]2[C:22](=[CH:23][CH:24]=1)[C:21](=O)[CH2:20][CH2:19][CH2:18]2>>[I:14][C:15]1[CH:16]=[C:17]2[C:22](=[CH:23][CH:24]=1)/[C:21](=[N:12]/[OH:13])/[CH2:20][CH2:19][CH2:18]2

Participants

3

Reactant 2

HCID 454898006-iodo-3,4-dihydronaphthalen-1(2H)-oneHCID 87295219(NE)-N-(5-ethenyl-2,3-dihydroinden-1-ylidene)hydroxylamine

Product 1

HCID 140592659(NE)-N-(6-iodo-3,4-dihydro-2H-naphthalen-1-ylidene)hydroxylamine

Procedure

The titled compound was prepared using the experimental protocol described for Preparation 87B employing 6-iodo-3,4-dihydronaphthalen-1(2H)-one as a starting material. The compound had an HPLC retention time=3.28 min. (condition C); LC/MS M+1=288.1.

Sources & evidence

ORD record
ord-408dcd7e99594248bd95bfb735ffff00
Source dataset
uspto-grants-2015_12
Patent number
US09216972B2

Reaction notes

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