HuagongsheHuagongshe Chemistry Print Report · For research reference only
Carbon Tetrachloride → Ethyl 2-chloro-2-(o-tolylimino)acetate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Carbon Tetrachloride | HCID 5943 | — |
| Reactant | Triphenylphosphine | HCID 11776 | — |
| Reactant | Ethyl [(2-methylphenyl)amino](oxo)acetate | HCID 366755 | — |
| Product | Ethyl 2-chloro-2-(o-tolylimino)acetate | HCID 90280270 | — |
Reaction Steps
The suspension of ethyl 2-oxo-2-(o-tolylamino)acetate (2.0 g, 10 mmol) and triphenylphosphine (4.0 g, 15 mmol) in carbon tetrachloride (150 mL) was refluxed overnight. The reaction was cooled down and filtered. The filtrate was collected and concentrated and used it without further purification. MS (m/z) 226 [M+H]+.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09220710B2 |
| Source dataset | uspto-grants-2015_12 |
| ORD ID | ord-e2541b6eee964802a631689e192c3bde |
| Source note | uspto-grants-2015_12 |