Carbon Tetrachloride → HCID 66789947, compound

HRID 1510128Notes

Reaction equation

HRID 1510128 reaction equation
[CH:1]1([CH:4]([C:6]2[CH:7]=[C:8]([CH2:12]O)[CH:9]=[CH:10][CH:11]=2)[CH3:5])[CH2:3][CH2:2]1.C1(P(C2C=CC=CC=2)C2C=CC=CC=2)C=CC=CC=1.C(Cl)(Cl)(Cl)[Cl:34]>>[Cl:34][CH2:12][C:8]1[CH:9]=[CH:10][CH:11]=[C:6]([CH:4]([CH:1]2[CH2:3][CH2:2]2)[CH3:5])[CH:7]=1

Participants

4

Reactant 3

HCID 5943Carbon TetrachlorideHCID 11776TriphenylphosphineHCID 66790199HCID 66790199, compound

Product 1

HCID 66789947HCID 66789947, compound

Conditions

Temperature
100 °C

Procedure

To a solution of [3-(1-cyclopropylethyl)phenyl]methanol (0.128 g, 0.73 mmol) in carbon tetrachloride (20 mL) was added polystyrene bound triphenyl phosphine (2.15 mmol/g, 0.68 g, 1.5 mmol). After stirring at 100° C. overnight the resin was filtered of and the solvent was removed under vacuum to afford the desired product.

Workup

  1. filtrationwas filtered of and the solvent
  2. customwas removed under vacuum

Sources & evidence

ORD record
ord-883c6888bee14bb59ad96abcc639773b
Source dataset
uspto-grants-2012_07
Patent number
US08211904B2

Reaction notes

Loading…