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HRID1510316

反应详情

EQUATION

反应方程式

HRID 1510316 的结构方程式

REACTANTS

反应物

1
结构：CC(C)(C)OC(=O)N1CCc2cc([N+](=O)[O-])ccc21
HCID54459059

未命名化合物

PRODUCTS

生成物

1
结构：CC(C)(C)OC(=O)N1CCc2cc(N)ccc21
HCID22240520

tert-Butyl 5-amino-2,3-dihydro-1H-indole-1-carboxylate

C13H18N2O2

AUXILIARIES

试剂、催化剂与溶剂

2
结构：[Pd]
催化剂HCID23938

Palladium

Pd

结构：CO
溶剂HCID887

Methanol

CH4O

PROCEDURE

实验过程

6.8 g tert-butyl 5-nitro-2,3-dihydro-indole-1-carboxylate are dissolved in 120 ml of methanol. To this are added 600 mg of palladium on charcoal (10%) and the mixture is hydrogenated for 1.5 hours at ambient temperature. Then the catalyst is filtered off and the solvent is eliminated in vacuo.

WORKUP

后处理

  1. filtrationThen the catalyst is filtered off