Stannous chloride dihydrate → HCID 961040, compound

HRID 1511508Notes

Reaction equation

HRID 1511508 reaction equation
[N+:1]([C:4]1[CH:9]=[CH:8][C:7]([Cl:10])=[CH:6][C:5]=1[C:11]1[S:12][C:13]2[CH:19]=[CH:18][CH:17]=[CH:16][C:14]=2[N:15]=1)([O-])=O.O.O.Cl[Sn]Cl>C(O)C>[NH2:1][C:4]1[CH:9]=[CH:8][C:7]([Cl:10])=[CH:6][C:5]=1[C:11]1[S:12][C:13]2[CH:19]=[CH:18][CH:17]=[CH:16][C:14]=2[N:15]=1

Participants

4

Reactant 2

HCID 61436Stannous chloride dihydrateHCID 54586297HCID 54586297, compound

Product 1

HCID 961040HCID 961040, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Conditions

Temperature
70 °C

Procedure

A mixture of 0.65 g (0.00223 mol) of 2-(2′-nitro-5′-chlorophenyl)benzothiazole OF31A and 2.52 g (0.01118 mol) of SnCl2.2H2O in 100 ml of ethanol was heated at 70° C. for 2 hours. A verification step using thin layer chromatography showed that the mixture no longer contained any starting reactant.

Sources & evidence

ORD record
ord-0a41144ca7974b38a0781cb1cb2ce5bc
Source dataset
uspto-grants-2012_07
Patent number
US08216800B2

Reaction notes

Loading…