Potassium Carbonate → HCID 67058155, compound

HRID 1515075Notes

Reaction equation

HRID 1515075 reaction equation
[CH2:1]([O:3][CH:4]([C:11]1[CH:16]=[CH:15][C:14]([OH:17])=[CH:13][CH:12]=1)[CH2:5][C:6]([O:8][CH2:9][CH3:10])=[O:7])[CH3:2].[N+:18]([C:21]1[CH:22]=[C:23]([CH:26]=[CH:27][CH:28]=1)[CH2:24]O)([O-:20])=[O:19].C(=O)([O-])[O-].[K+].[K+]>CC(C)=O>[CH2:1]([O:3][CH:4]([C:11]1[CH:12]=[CH:13][C:14]([O:17][CH2:24][C:23]2[CH:26]=[CH:27][CH:28]=[C:21]([N+:18]([O-:20])=[O:19])[CH:22]=2)=[CH:15][CH:16]=1)[CH2:5][C:6]([O:8][CH2:9][CH3:10])=[O:7])[CH3:2]

Participants

5

Reactant 3

HCID 11430Potassium CarbonateHCID 692673-Nitrobenzyl alcoholHCID 67058135Ethyl 3-ethoxy-3-(4-hydroxyphenyl)propionate

Product 1

HCID 67058155HCID 67058155, compound

Reagents, catalysts & solvents 1

HCID 180AcetoneSolvent

Procedure

Ethyl 3-ethoxy-3-(4-hydroxyphenyl)propionate (200 mg, 0.839 mmol) produced in Example 1 (1C) and 3-nitrobenzyl alcohol (200 mg, 0.926 mmol) were dissolved in acetone (4 mL), and potassium carbonate (136 mg, 0.984 mmol) were added thereto at room temperature, and then, the resulting mixture was stirred at room temperature for 12 hours.

Sources & evidence

ORD record
ord-621e2e11d6e34ae4aa717b28e88537e0
Source dataset
uspto-grants-2012_07
Patent number
US08222281B2

Reaction notes

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