Raffinose, pentahydrate → Raffinose

HRID 1518610Notes

Reaction equation

HRID 1518610 reaction equation
[CH2:1]([OH:34])[C@H:2]1[O:7][C@H:6]([O:8][CH2:9][C@H:10]2[O:15][C@H:14]([O:16][C@:17]3([CH2:26][OH:27])[O:21][C@H:20]([CH2:22][OH:23])[C@@H:19]([OH:24])[C@@H:18]3[OH:25])[C@H:13]([OH:28])[C@@H:12]([OH:29])[C@@H:11]2[OH:30])[C@H:5]([OH:31])[C@@H:4]([OH:32])[C@H:3]1[OH:33].O.O.O.O.O.O.[O:41]=[CH:42][C@@H:43]([C@H:45]([C@@H:47]([C@@H:49]([CH2:51][OH:52])[OH:50])[OH:48])[OH:46])[OH:44]>O>[CH2:1]([OH:34])[C@H:2]1[O:7][C@H:6]([O:8][CH2:9][C@H:10]2[O:15][C@H:14]([O:16][C@:17]3([CH2:26][OH:27])[O:21][C@H:20]([CH2:22][OH:23])[C@@H:19]([OH:24])[C@@H:18]3[OH:25])[C@H:13]([OH:28])[C@@H:12]([OH:29])[C@@H:11]2[OH:30])[C@H:5]([OH:31])[C@@H:4]([OH:32])[C@H:3]1[OH:33].[O:41]=[CH:42][C@@H:43]([C@H:45]([C@@H:47]([C@@H:49]([CH2:51][OH:52])[OH:50])[OH:48])[OH:46])[OH:44]

Participants

5

Reactant 2

HCID 2724100Raffinose, pentahydrateHCID 22814120Glucose Monohydrate

Product 2

HCID 107526(2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanalHCID 439242RaffinoseYield 4.5%

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

Raffinose pentahydrate or glucose monohydrate was dissolved in nano-pure water to obtain 4.5% (w/v) raffinose or glucose. To the solution, leucine was added and the pH was adjusted to 7.0. The concentration of the leucine in the solution ranged between 0.8% and 1.6% (w/v).

Sources & evidence

ORD record
ord-856333b9505d437b9cb299b1db0cbd23
Source dataset
uspto-grants-2015_07
Patent number
US09072783B2

Reaction notes

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