Ammonium cerium (IV) nitrate → HCID 178429420, compound

HRID 1529170Notes

Reaction equation

HRID 1529170 reaction equation
[F:1][C:2]1[CH:3]=[C:4]2[C:10]([C:11]3[N:12]=[N:13][C:14]4[C:19]([CH3:21])([CH3:20])[C:18](=[O:22])[N:17]([CH2:23][O:24][CH2:25][CH2:26][Si:27]([CH3:30])([CH3:29])[CH3:28])[C:15]=4[N:16]=3)=[N:9][N:8](CC3C=CC(OC)=CC=3)[C:5]2=[N:6][CH:7]=1.[N+]([O-])([O-])=O.[Ce+4].[NH4+].[N+]([O-])([O-])=O.[N+]([O-])([O-])=O.[N+]([O-])([O-])=O.[N+]([O-])([O-])=O>C(#N)C.O>[F:1][C:2]1[CH:3]=[C:4]2[C:10]([C:11]3[N:12]=[N:13][C:14]4[C:19]([CH3:20])([CH3:21])[C:18](=[O:22])[N:17]([CH2:23][O:24][CH2:25][CH2:26][Si:27]([CH3:29])([CH3:28])[CH3:30])[C:15]=4[N:16]=3)=[N:9][NH:8][C:5]2=[N:6][CH:7]=1

Participants

5

Reactant 2

HCID 9869224Ammonium cerium (IV) nitrateHCID 70981725HCID 70981725, compound

Product 1

HCID 178429420HCID 178429420, compound

Reagents, catalysts & solvents 2

HCID 962WaterSolvent2×HCID 6342AcetonitrileSolvent

Procedure

4.148 g (7.546 mmol) of the compound from Example 35A were taken up in acetonitrile (110 ml) and water (55 ml), 12.411 g (22.638 mmol) of ammonium cerium(IV) nitrate were added and the mixture was stirred at room temperature for 20 min. Plenty of water was then added, and a precipitate was filtered off. This solid was washed with water and then with a little diethyl ether. This gave, after drying under high vacuum, 1.53 g (47% of theory) of the title compound.

Workup

  1. filtrationa precipitate was filtered off
  2. washThis solid was washed with water
  3. dry with materialThis gave, after drying under high vacuum, 1.53 g (47% of theory) of the title compound

Sources & evidence

ORD record
ord-6f8f0f85b9294d7da05c3187b2c57299
Source dataset
uspto-grants-2015_07
Patent number
US09090610B2

Reaction notes

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