Ammonium cerium (IV) nitrate → HCID 178429420, compound

Participants

Reaction Steps

4.148 g (7.546 mmol) of the compound from Example 35A were taken up in acetonitrile (110 ml) and water (55 ml), 12.411 g (22.638 mmol) of ammonium cerium(IV) nitrate were added and the mixture was stirred at room temperature for 20 min. Plenty of water was then added, and a precipitate was filtered off. This solid was washed with water and then with a little diethyl ether. This gave, after drying under high vacuum, 1.53 g (47% of theory) of the title compound.

Provenance & Evidence